First option: Create a TB style back-up and select everything, install TB on your new pc and tell it it restore accounts from your back-up. This has the disadvantage that all of your paths have to be the same on your old and new system.
Second option: Start Regedit on your old pc and export the key "HKEY_CURRENT_USER\Software\RIT\The Bat!" to a file (call it TB.reg)
Now copy both your mail directory and this TB.reg file to your new pc. When you don't place your mail directory to the same path as it was on your old pc, that's no problem, it can be remedied this way.
In order to restore the registry settings, you open the TB.reg file, this will prompt the question whether you want add the contents to the registry and of course you say 'yes'
Now if you're using a different path to your mail directory, just start regedit and adjust the key "HKEY_CURRENT_USER\Software\RIT\The Bat!\Working Directory" to your liking.
Now you install TB and it'll accept the settings.
In case you don't like to play with your registry, you can also forget about that part and only copy your mail directory.
After installing TB you tell it to create new acccounts. Point it to your copied mail directory and tell TB to use accounts with the existing names, TB will take those settings.
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I'm just a user of The Bat! I don't work for Ritlabs.